Degreasing & Derusting Formulation for Trication phosphating process

Dr E. Ramanathan PhD

Typical Degreasing Concentrate Formula

Used prior to trication phosphating to ensure optimal surface preparation.


1. Alkaline Degreasing Concentrate Formula (by weight %)

For oily steel surfaces; suitable for spray or dip.

Ingredient% w/w
Sodium metasilicate (5H₂O)25.0
Sodium carbonate (soda ash)20.0
Sodium hydroxide (flakes)10.0
Non-ionic surfactant (e.g., NP-10)5.0
EDTA (optional, for hardness control)1.0
Sodium gluconate (optional chelator)2.0
Water (to make 100%)37.0

Use dilution: 3–5% in water
Operating temp: 50–70°C
pH: >11


2. Derusting / Pickling Concentrate Formula (Mild Acid Type)

For removal of rust/mill scale after degreasing.

Ingredient% w/w
Phosphoric acid (85%)50.0
Non-ionic surfactant1.0
Thiourea (acid inhibitor)0.5
Benzotriazole (flash rust inhibitor)0.5
Water48.0

Use dilution: 10–20% in water
Operating temp: ambient to 50°C
Contact time: 3–10 minutes


Notes:

  • For heavy-duty degreasing, increase NaOH and use a stronger emulsifier.
  • For derusting, inhibit strongly if steel is to be exposed after treatment.
  • Always rinse thoroughly after both degreasing and pickling to remove residues.

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