Aluminium Types and Selection of Cleaning Chemicals

Dr E. Ramanathan PhD

Aluminium comes in various grades and alloys, which differ in composition, surface properties, and reactivity. Selecting a suitable degreasing cleaner depends on the aluminium type and the process that follows (e.g., painting, anodizing, welding).


1. Pure Aluminium (1000 series – e.g., 1050, 1100)

  • Properties: Soft, ductile, highly corrosion resistant.
  • Cleaner Type: Mild alkaline or neutral degreaser.
  • Reason: Highly reactive to strong alkalis; avoid caustic cleaners.

2. Work-Hardening Alloys (3000 series – e.g., 3003)

  • Properties: Moderate strength, good corrosion resistance.
  • Cleaner Type: Mild alkaline or weak acidic degreaser.
  • Reason: Avoid high-pH cleaners that may cause surface darkening.

3. Heat-Treatable Alloys (2000 & 7000 series – e.g., 2024, 7075)

  • Properties: High strength, prone to galvanic corrosion.
  • Cleaner Type: Neutral or mildly acidic cleaner with corrosion inhibitors.
  • Reason: Sensitive to both acidic and alkaline attack.

4. Structural Alloys (5000 series – e.g., 5052, 5083)

  • Properties: High corrosion resistance, used in marine/architectural.
  • Cleaner Type: Mild alkaline or neutral degreaser.
  • Reason: More stable, but avoid aggressive alkalis.

5. Casting Alloys (e.g., A356, 319)

  • Properties: High silicon content, porous surface.
  • Cleaner Type: Neutral or weak alkaline cleaner.
  • Reason: Highly reactive; avoid acids which penetrate porosity.

6. Anodized Aluminium

  • Properties: Pre-treated surface with oxide layer.
  • Cleaner Type: pH-neutral cleaner only.
  • Reason: Acid or alkali may damage the oxide layer.

Selection Chart:

Aluminium TypeRecommended Cleaner TypeNotes
1000 seriesMild alkaline or neutralAvoid caustic soda
3000 seriesMild alkaline or weak acidicBalanced cleaning with inhibitor
2000 / 7000 seriesNeutral or weak acidic + inhibitorProne to pitting
5000 seriesMild alkaline or neutralGood tolerance
Cast AluminiumNeutral or weak alkalineAvoid acids
Anodized AluminiumNeutral onlyPreserve anodic layer

Formulation of Aluminium Cleaners

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